Issue 18, 2001
From the journal:

Chemical Communications

Solid state evidence for π-complexation of sodium cation by carbon–carbon double bonds

Jiaxin Hu,a   Leonard J. Barbourb  and  George W. Gokel*a  

* Corresponding authors

a Bioorganic Chemistry Program and, Dept. of Molecular Biology and Pharmacology, Washington University School of Medicine, 660 South Euclid Ave., Campus Box 8103, St. Louis, MO, USA.
E-mail: ggokel@molecool.wustl.edu

b Department of Chemistry, University of Missouri, 601 S. College Ave., Columbia, MO, USA

Abstract

Solid state evidence shows that neutral double bonds, attached to flexible sidearms of a lariat ether, serve as intramolecular π-donors for a ring-bound Na+ cation.

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Article information

DOI
https://doi.org/10.1039/B106589K
Article type
Communication
Submitted
25 May 2001
Accepted
13 Jul 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1858-1859

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Solid state evidence for π-complexation of sodium cation by carbon–carbon double bonds

J. Hu, L. J. Barbour and G. W. Gokel, Chem. Commun., 2001, 1858 DOI: 10.1039/B106589K

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