Issue 18, 2001
From the journal:

Chemical Communications

1,2,4,3,5-Benzotrithiadiazepine and its unexpected hydrolysis to unusual 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine

Alexander Yu. Makarov,a   Makhmut M. Shakirov,a   Konstantin V. Shuvaev,b   Irina Yu. Bagryanskaya,a   Yuri V. Gatilova  and  Andrey V. Zibarev*a  

* Corresponding authors

a Institute of Organic Chemistry, Russian Academy of Sciences, Novosibirsk, Russia.
E-mail: zibarev@nioch.nsc.ru

b Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russia

Abstract

Previously unknown 1,2,4,3,5-benzotrithiadiazepine 1 was prepared by 1∶1 condensation of Ph-N[double bond, length half m-dash]S[double bond, length half m-dash]N-SiMe3 with S2Cl2 followed by intramolecular ortho-cyclization of [Ph-N[double bond, length half m-dash]S[double bond, length half m-dash]N-S-S-Cl] intermediate, and hydrolyzed in pyridine to unusual macrocyclic 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine 2.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B105001J
Article type
Communication
Submitted
06 Jun 2001
Accepted
02 Aug 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1774-1775

Permissions

Request permissions

1,2,4,3,5-Benzotrithiadiazepine and its unexpected hydrolysis to unusual 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine

A. Yu. Makarov, M. M. Shakirov, K. V. Shuvaev, I. Yu. Bagryanskaya, Y. V. Gatilov and A. V. Zibarev, Chem. Commun., 2001, 1774 DOI: 10.1039/B105001J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements