Issue 18, 2001
From the journal:

Chemical Communications

Synthesis of alkenylene-bridged macrocyclic silsesquioxanes by ruthenium or rhodium-catalyzed ring-closing reactions of bis(allyldimethylsilyl) groupsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b1/b104086n/

Kenji Wada,a   Daisuke Izuhara,a   Koichi Yamada,a   Masashi Shiotsuki,a   Teruyuki Kondoa  and  Take-aki Mitsudo*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, Japan

Abstract

Novel alkenylene-bridged oligosilsesquioxanes composed of half-caged structures with 16- or 17-membered rings as well as a titanium-containing molecule with a twisted 21-membered macrocycle have been synthesized by ruthenium or rhodium-catalyzed ring-closing reactions of silsesquioxanes with bis(allyldimethylsilyl) groups.

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DOI
https://doi.org/10.1039/B104086N
Article type
Communication
Submitted
09 May 2001
Accepted
07 Aug 2001
First published
05 Sep 2001

Chem. Commun., 2001, 1802-1803

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Synthesis of alkenylene-bridged macrocyclic silsesquioxanes by ruthenium or rhodium-catalyzed ring-closing reactions of bis(allyldimethylsilyl) groups

K. Wada, D. Izuhara, K. Yamada, M. Shiotsuki, T. Kondo and T. Mitsudo, Chem. Commun., 2001, 1802 DOI: 10.1039/B104086N

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