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Issue 18, 2001
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Synthesis of alkenylene-bridged macrocyclic silsesquioxanes by ruthenium or rhodium-catalyzed ring-closing reactions of bis(allyldimethylsilyl) groups

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Abstract

Novel alkenylene-bridged oligosilsesquioxanes composed of half-caged structures with 16- or 17-membered rings as well as a titanium-containing molecule with a twisted 21-membered macrocycle have been synthesized by ruthenium or rhodium-catalyzed ring-closing reactions of silsesquioxanes with bis(allyldimethylsilyl) groups.

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Publication details

The article was received on 09 May 2001, accepted on 07 Aug 2001 and first published on 05 Sep 2001


Article type: Communication
DOI: 10.1039/B104086N
Citation: Chem. Commun., 2001, 1802-1803
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    Synthesis of alkenylene-bridged macrocyclic silsesquioxanes by ruthenium or rhodium-catalyzed ring-closing reactions of bis(allyldimethylsilyl) groups

    K. Wada, D. Izuhara, K. Yamada, M. Shiotsuki, T. Kondo and T. Mitsudo, Chem. Commun., 2001, 1802
    DOI: 10.1039/B104086N

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