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Issue 14, 2001
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Synthesis and structural characterisation of a boralumoxane capable of activating a zirconocene ethene polymerisation catalyst

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Abstract

The reaction of But3Al with ArB(OH)2 (Ar = 2,6-diisopropylphenyl) leads, via the intermediate [But2Al(O)BAr(OH)]2  1, to the crystallographically characterised boralumoxane Al(But2Al)(ButAl)2(O2 BAr)4  3 which is able to activate Cp2ZrMe2 to effect catalytic ethene polymerisation.

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Publication details

The article was received on 24 Apr 2001, accepted on 01 Jun 2001 and first published on 27 Jun 2001


Article type: Communication
DOI: 10.1039/B103670J
Citation: Chem. Commun., 2001, 1286-1287
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    Synthesis and structural characterisation of a boralumoxane capable of activating a zirconocene ethene polymerisation catalyst

    B. Richter, A. Meetsma, B. Hessen and J. H. Teuben, Chem. Commun., 2001, 1286
    DOI: 10.1039/B103670J

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