Issue 17, 2001
From the journal:

Chemical Communications

Asymmetric trialkylaluminium addition to aldehydes catalyzed by titanium complexes of N-sulfonylated amino alcohols with two stereogenic centers

Jing-Song You,†a   Sheng-Hsiang Hsieha  and  Han-Mou Gau*a  

* Corresponding authors

a Department of Chemistry, National Chung-Hsing University, Taichung, Taiwan
E-mail: hmgau@dragon.nchu.edu.tw

Abstract

The asymmetric methylation, ethylation and allylation of aldehydes using trialkylaluminium reagents catalyzed by titanium(IV) complexes of N-sulfonylated amino alcohols gave excellent enantioselectivities of up to 99% ee.

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Article information

DOI
https://doi.org/10.1039/B103618C
Article type
Communication
Submitted
23 Apr 2001
Accepted
20 Jun 2001
First published
01 Aug 2001

Chem. Commun., 2001, 1546-1547

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Asymmetric trialkylaluminium addition to aldehydes catalyzed by titanium complexes of N-sulfonylated amino alcohols with two stereogenic centers

J. You, S. Hsieh and H. Gau, Chem. Commun., 2001, 1546 DOI: 10.1039/B103618C

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