Issue 14, 2001
From the journal:

Chemical Communications

Observation of a stable cis-diphosphine solvate rhodium dihydride derived from PHANEPHOS

Hanjo Heinrich,a   Ralf Giernoth,b   Joachim Bargon*a  and  John M. Brown*b  

* Corresponding authors

a Institute of Physical and Theoretical Chemistry, University of Bonn, Wegelerstr. 12, Bonn, Germany.
E-mail: bargon@uni-bonn.de

b Dyson Perrins Laboratory, South Parks Road, Oxford, UK
E-mail: bjm@ermine.ox.ac.uk

Abstract

The methanol solvate rhodium(PHANEPHOS) forms a stable dihydride which has been characterised in solution by NMR as a pair of equilibrating diastereomers.

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Article information

DOI
https://doi.org/10.1039/B102316K
Article type
Communication
Submitted
12 Mar 2001
Accepted
24 May 2001
First published
27 Jun 2001

Chem. Commun., 2001, 1296-1297

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Observation of a stable cis-diphosphine solvate rhodium dihydride derived from PHANEPHOS

H. Heinrich, R. Giernoth, J. Bargon and J. M. Brown, Chem. Commun., 2001, 1296 DOI: 10.1039/B102316K

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