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Unexpected bonding similarities between the bridging metalloligands [MoCp(CO)3] and [PtI(CO)2(PPh3)] acting as 4-electron donors in metal clusters. Crystal structures of [Pt2Mo(μ-CO)3- (μ-PPh2)Cp(PPh3)2] and [Pt3(μ-CO)2(μ-PPh2)I(PPh3)3]

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a
Laboratoire de Chimie de Coordination, UMR 7513 CNRS, Institut Le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, Strasbourg Cedex, France.
E-mail: braunst@chimie.u-strasbg.fr
b
Institut de Chimie, Université de Constantine, route de AÏn el Bey, Constantine, Algeria
c
Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR 6511 CNRS, Institut de Chimie, Université de Rennes 1, Campus de Beaulieu, Rennes Cedex, France
Chem. Commun., 2001, 849-850

DOI: 10.1039/B101410M
Received 13 Feb 2001, Accepted 22 Mar 2001
First published online 17 Apr 2001
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