Issue 12, 2001
From the journal:

Chemical Communications

Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

Luis D. Mirandaa  and  Samir Z. Zard*a  

* Corresponding authors

a Institut de Chimie des Substances Naturelles, CNRS, Gif-Sur-Yvette, France.
E-mail: zard@icns.cnrs-gif.fr

b Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, Palaiseau, France

Abstract

The previously described, highly stereoselective ring-closure of δ-unsaturated tosylhydrazones upon reduction with borohydride may not be a radical process but rather an ene-type concerted transformation of the intermediate monosubstituted diimide.

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Article information

DOI
https://doi.org/10.1039/B101053K
Article type
Communication
Submitted
30 Jan 2001
Accepted
27 Mar 2001
First published
22 May 2001

Chem. Commun., 2001, 1068-1069

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Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

L. D. Miranda and S. Z. Zard, Chem. Commun., 2001, 1068 DOI: 10.1039/B101053K

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