Issue 4, 2001
From the journal:

Chemical Communications

New paramagnetic ruthenium complexes via one-electron reduction of metallacumulenesElectronic supplementary information (ESI) available: selected spectroscopic data. See http://www.rsc.org/suppdata/cc/b0/b008893p/

Stéphane Rigaut,*a   Olivier Maury,a   Daniel Touchard*a  and  Pierre H. Dixneufa  

* Corresponding authors

a Institut de Chimie de Rennes, UMR 6509 CNRS-Université de Rennes: Organométalliques et Catalyse, Campus de Beaulieu 35042, Rennes, France.
E-mail: daniel.touchard@univ-rennes1.fr

Abstract

One-electron reductions of [Cl(dppe)2Ru[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]CR2]PF6 (R = Ph, Me) and [Cl(dppe)2Ru[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]CPh 2]PF6 with Co(C5H5)2 provide radical species with the unpaired electron localized on the trisubstituted carbon atom of the cumulene moiety as shown by hydrogen atom capture and EPR spectroscopy.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B008893P
Article type
Communication
Submitted
06 Nov 2000
Accepted
11 Jan 2001
First published
08 Feb 2001

Chem. Commun., 2001, 373-374

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New paramagnetic ruthenium complexes via one-electron reduction of metallacumulenes

S. Rigaut, O. Maury, D. Touchard and P. H. Dixneuf, Chem. Commun., 2001, 373 DOI: 10.1039/B008893P

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