Issue 23, 2000

Anionic metal dicyanamide networks with paramagnetic counter-

Abstract

The M(bipy)32+ cations in the isomorphous structures of [M(bipy)3][M′(dca)3]2, [dca = dicyanamide, N(CN)2; M = Fe, M′ = Mn 1, Fe 2 or M = Ni, M′ = Mn 3] are contained within hexagonal windows of anionic 2D (6,3) M(dca)3 sheets; weak antiferromagnetic coupling is observed between metal centres within the anionic networks of all three compounds.

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2000
Accepted
18 Oct 2000
First published
10 Nov 2000

Chem. Commun., 2000, 2331-2332

Anionic metal dicyanamide networks with paramagnetic counter-cations

S. R. Batten, P. Jensen, B. Moubaraki and K. S. Murray, Chem. Commun., 2000, 2331 DOI: 10.1039/B007080G

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