Structure and magnetic properties of a nickel(II) complex of a tridentate verdazyl radical: strong ferromagnetic metal-radical exchange coupling

Tosha M. Barclay; Robin G. Hicks; Martin T. Lemaire; Laurence K. Thompson

doi:10.1039/B006520J

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Structure and magnetic properties of a nickel(ii) complex of a tridentate verdazyl radical: strong ferromagnetic metal-radical exchange couplingElectronic supplementary information (ESI) available: partial packing diagram for 1. See http://www.rsc.org/suppdata/cc/b0/b006520j/

Tosha M. Barclay,^a Robin G. Hicks,*^b Martin T. Lemaire^b and Laurence K. Thompson^c

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* Corresponding authors

^a Department of Chemistry, Box 9573, Mississippi State University, Mississippi State MS 39762-9573, USA

^b Department of Chemistry, University of Victoria, PO Box 3065, Victoria, B.C. V8W 3V6, Canada.
E-mail: rhicks@uvic.ca

^c Department of Chemistry, Memorial University of Newfoundland, Nfld., St. Johns, Canada

Abstract

Magnetic susceptibility measurements on a structurally characterized nickel(II) complex of a tridentate verdazyl radical indicate very strong ferromagnetic Ni–verdazyl intramolecular exchange interactions (J > +200 cm⁻¹).

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DOI: https://doi.org/10.1039/B006520J
Article type: Communication
Submitted: 01 Aug 2000
Accepted: 25 Sep 2000
First published: 18 Oct 2000

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Chem. Commun., 2000, 2141-2142

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Structure and magnetic properties of a nickel(II) complex of a tridentate verdazyl radical: strong ferromagnetic metal-radical exchange coupling

T. M. Barclay, R. G. Hicks, M. T. Lemaire and L. K. Thompson, Chem. Commun., 2000, 2141 DOI: 10.1039/B006520J

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Chemical Communications

Structure and magnetic properties of a nickel(ii) complex of a tridentate verdazyl radical: strong ferromagnetic metal-radical exchange couplingElectronic supplementary information (ESI) available: partial packing diagram for 1. See http://www.rsc.org/suppdata/cc/b0/b006520j/

Abstract

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Article information

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Structure and magnetic properties of a nickel(II) complex of a tridentate verdazyl radical: strong ferromagnetic metal-radical exchange coupling

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