Issue 19, 2000
From the journal:

Chemical Communications

A novel synthetic route to peralkylated carborane anions, 1-H-CB9Me9− and 1-H-CB11R11− (R = Me, Et)

Chi-Wing Tsanga  and  Zuowei Xie*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China.
E-mail: zxie@cuhk.edu.hk

Abstract

Treatment of carborane anions with excess RBr (R = Me, Et) in a sealed Pyrex tube at 200 °C gives peralkylated carborane anions in quantitative yields, which represents the most convenient and the most economic method so far reported in the literature for the preparation of peralkylcarborane anions.

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Article information

DOI
https://doi.org/10.1039/B004737F
Article type
Communication
Submitted
13 Jun 2000
Accepted
22 Aug 2000
First published
11 Sep 2000

Chem. Commun., 2000, 1839-1840

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A novel synthetic route to peralkylated carborane anions, 1-H-CB9Me9− and 1-H-CB11R11− (R = Me, Et)

C. Tsang and Z. Xie, Chem. Commun., 2000, 1839 DOI: 10.1039/B004737F

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