Equimolar mixtures of NMRP and ATRP initiators lead to polystyrene that is unimodal by GPC; the mechanism of action most consistent with the data suggests that under the reaction conditions, TEMPO and Cl end groups scramble rapidly relative to the propagation rate, and result in a single type of polymer chain.
Simultaneous atom transfer and nitroxide mediated controlled free radical polymerization of styrene
M. R. Korn and M. R. Gagné, Chem. Commun., 2000, 1711 DOI: 10.1039/B004157M
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