Issue 13, 2000
From the journal:

Chemical Communications

Synthesis and coordinative properties of a hybrid bis(diphenylphosphino)methane–terpyridine

Guillaume Pickaert,a   Michèle Cesario,b   Laurent Doucea  and  Raymond Ziessel*a  

* Corresponding authors

a Laboratoire de Chimie, d’Electronique et Photonique Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux, Université Louis Pasteur, 25 rue Becquerel, F-67087 Strasbourg Cedex 02, France.
E-mail: ziessel@chimie.u-strasbg.fr

b Institut de Chimie des Substances Naturelles, CNRS, F-91128 Gif-sur-Yvette, France

Abstract

A newly-synthesized 4′-[bis(diphenylphosphino)methane]–2,2′∶6′,2 ″-terpyridine-based (dppm–terpy) ligand forms complexes by selective complexation of the terpy or diphos segment, respectively, with Fe(II) or Pd(II) salts; in the latter case, an X-ray structural analysis reveals the formation of a neutral square-planar complex assembled from the deprotonated ligands.

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Article information

DOI
https://doi.org/10.1039/B002586K
Article type
Communication
Submitted
31 Mar 2000
Accepted
15 May 2000
First published
16 Jun 2000

Chem. Commun., 2000, 1125-1126

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Synthesis and coordinative properties of a hybrid bis(diphenylphosphino)methane–terpyridine

G. Pickaert, M. Cesario, L. Douce and R. Ziessel, Chem. Commun., 2000, 1125 DOI: 10.1039/B002586K

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