Issue 11, 2000
From the journal:

Chemical Communications

A new open-framework fluorinated gallium phosphate with large 18-ring channels (MIL-31)

Capucine Sassoye,a   Thierry Loiseau,a   Francis Taulelleb  and  Gérard Férey*a  

* Corresponding authors

a Institut Lavoisier, UMR CNRS 8637, Université de Versailles St Quentin, 45, Avenue des Etats-Unis, Versailles cedex, France.
E-mail: ferey@chimie.uvsq.fr

b Laboratoire de RMN et Chimie du Solide, UMR Brüker-CNRS-ULP 7510, Institut Le Bel, Université Louis Pasteur, 4, rue Blaise Pascal, Strasbourg, France

Abstract

A new open-framework fluorinated gallium phosphate (MIL-31) containing the Ga9(PO4)9(H2O)(OH)(OH,F)4 5− anion was hydrothermally synthesized by using long alkyl chain diamines (C9 and C10) as structure-directing agents; its crystal structure is built up from hexameric units and exhibits large one-dimensional hexagonal channels delimited by 18-rings.

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Article information

DOI
https://doi.org/10.1039/B001948H
Article type
Communication
Submitted
09 Mar 2000
Accepted
26 Apr 2000
First published
16 May 2000

Chem. Commun., 2000, 943-944

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A new open-framework fluorinated gallium phosphate with large 18-ring channels (MIL-31)

C. Sassoye, T. Loiseau, F. Taulelle and G. Férey, Chem. Commun., 2000, 943 DOI: 10.1039/B001948H

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