Issue 11, 2000
From the journal:

Chemical Communications

New FeS clusters with NO: associative formation of [Fe5S4(NO)8] and [Fe7S6(NO)10], and larger clusters

Mark Lewin,   Keith Fisher  and  Ian Dance  

Abstract

Solutions of [Fe2S2(NO)4]2− or [Fe4S3(NO)7]− undergo facile aggregation to new clusters [Fe5S4(NO)8]− and [Fe7S6(NO)10]−, but do not form the known species [Fe4S4-(NO)4]z and [Fe6S6(NO)6]2−; reactivities and reactions in solution and gas phases were monitored by electrospray Fourier transform ion cyclotron resonance mass spectrometry, and the probable structures of [Fe5S4(NO)8]− and [Fe7S6(NO)10]− were determined by density functional calculations.

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Article information

DOI
https://doi.org/10.1039/B001738H
Article type
Paper

Chem. Commun., 2000, 947-948

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New FeS clusters with NO: associative formation of [Fe5S4(NO)8] and [Fe7S6(NO)10], and larger clusters

M. Lewin, K. Fisher and I. Dance, Chem. Commun., 2000, 947 DOI: 10.1039/B001738H

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