Issue 1, 2000

Photoactivated DNA cleavage via charge transfer promoted N2 release from tris[3-hydroxy-1,2,3-benzotriazine-4(3H)-one]iron(III)

Abstract

Visible wavelength ligand-to-metal (LMCT) activated N2 release from tris(3-hydroxy-1,2,3-benzotriazine-4(3H)-one]iron(III) produces localized ligand radical intermediates capable of cleaving DNA and represents a new chemical approach to photonuclease design for biological applications.

Article information

Article type
Communication
Submitted
05 Oct 1999
Accepted
18 Nov 1999
First published
06 Jan 2000

Chem. Commun., 2000, 69-70

Photoactivated DNA cleavage via charge transfer promoted N2 release from tris[3-hydroxy-1,2,3-benzotriazine-4(3H)-one]iron(III)

T. D. Maurer, B. J. Kraft, S. M. Lato, A. D. Ellington and J. M. Zaleski, Chem. Commun., 2000, 69 DOI: 10.1039/A908005H

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