The origin of the second, faster relaxation process in Mn12 molecules has been identified as a different relative orientation of the Jahn–Teller elongation axes of the MnIII ions, which we have termed ‘Jahn–Teller isomerism’.
Z. Sun, D. Ruiz, D. N. Hendrickson, N. R. Dilley, M. Brian Maple, M. Soler, K. Folting, G. Christou and J. Ribas, Chem. Commun., 1999, 1973 DOI: 10.1039/A906451F
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