Issue 18, 1999
From the journal:

Chemical Communications

Effect of competing π-donor N-bound ligands on structure and bonding. Synthesis and structure of tungsten organoimido nitrido complexes

Caroll E. Pohl-Ferry,   Joseph W. Ziller  and  Nancy M. Doherty  

Abstract

Tungsten organoimido nitrido compounds, [W2(N)- (NR)2Cl5]3 (R = Et, C6H4Me-p), form in high yield in the reactions of W(NR)Cl4 with N(SiMe3)3 and adopt structures in solution and the solid state consisting of chloro-bridged trimers of mononitrido-bridged di(organoimidotungsten) units with an unusual geometry that allows maximum π-donation from the imido and nitrido ligand set.

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Article information

DOI
https://doi.org/10.1039/A906037E
Article type
Paper

Chem. Commun., 1999, 1815-1816

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Effect of competing π-donor N-bound ligands on structure and bonding. Synthesis and structure of tungsten organoimido nitrido complexes

C. E. Pohl-Ferry, J. W. Ziller and N. M. Doherty, Chem. Commun., 1999, 1815 DOI: 10.1039/A906037E

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