Issue 16, 1999

Topological control in coordination polymers by non-covalent forces

Abstract

Reaction of Zn2+ salts with the terephthalate dianion results in a herringbone motif coordination polymer; the orientation of the terephthalate spacer ligands and the coordination geometry about the Zn2+ ion is crucially dependent on hydrogen bonding to ancillary ligands; replacement of coordinated water with ethylenediamine results in marked changes to the polymer orientation without disruption of the fundamental features of the material.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 1563-1564

Topological control in coordination polymers by non-covalent forces

G. Guilera and J. W. Steed, Chem. Commun., 1999, 1563 DOI: 10.1039/A903163D

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