Issue 13, 1999

Ligand reorganization energies as a basis for the design of synergistic metal ion extraction systems

Abstract

In the extraction of alkaline earth cations by acidic organophosphorus extractants, a correlation has been demonstrated between the effectiveness of the stereoisomers of dicyclohexano-18-crown-6 as synergists and the strain energy associated with conversion of the unbound crown ether to its complexed form.

Article information

Article type
Paper

Chem. Commun., 1999, 1177-1178

Ligand reorganization energies as a basis for the design of synergistic metal ion extraction systems

M. L. Dietz, A. H. Bond, R. Chiarizia, V. J. Huber, A. W. Herlinger and B. P. Hay, Chem. Commun., 1999, 1177 DOI: 10.1039/A902842K

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