Results from incorporation studies with 13C-labelled acetate, propionate and proline establish a polyketide origin for the pyrrole-containing streptomycete metabolite, XR587, and are in accord with the formation of an amide bond via an unprecedented rearrangement of a proline-derived starter unit.
M. E. Raggatt, T. J. Simpson and S. K. Wrigley, Chem. Commun., 1999, 1039 DOI: 10.1039/A902777G
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