Issue 20, 1998
From the journal:

Chemical Communications

[Tl(OPPh3)2][Au(C6F5)2]: the first extended unsupported gold–thallium linear chain

Olga Crespo,   Antonio Laguna,   Eduardo J. Fernández,   José M. López-de-Luzuriaga,   Aránzazu Mendía,   Miguel Monge,   Elena Olmos  and  Peter G. Jones  

Abstract

Li[Au(C6F5)2] reacts with TlNO3 in the presence of OPPh3 affording a complex of stoichiometry [AuTl(C6F5)2- (OPPh3)2]n, which presents different luminescence properties depending on the conditions and whose crystal structure reveals the existence of unsupported Au–Tl bonds forming a polymeric linear chain.

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Article information

DOI
https://doi.org/10.1039/A806077K
Article type
Paper

Chem. Commun., 1998, 2233-2234

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[Tl(OPPh3)2][Au(C6F5)2]: the first extended unsupported gold–thallium linear chain

O. Crespo, A. Laguna, E. J. Fernández, J. M. López-de-Luzuriaga, A. Mendía, M. Monge, E. Olmos and P. G. Jones, Chem. Commun., 1998, 2233 DOI: 10.1039/A806077K

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