First of a new family of tetraamine bis(µ-thiolate)-containing macrocycles: structure and stepwise oxidations and reductions of the dinickel(II) complex
Abstract
Reduction of a dinickel(II) dithiolate Schiff-base macrocyclic complex with sodium borohydride results in a ‘bowl’-shaped dinickel(II) dithiolate amine macrocyclic complex which exhibits four separate one-electron redox processes.