Issue 18, 1998

The cyanate ion as a bridging ligand between lanthanide and transition metals. Formation of one-dimensional extended arrays {(DMF)6Ln2Ni(NCO)8} (Ln = Sm, Eu) and monomeric complexes (DMF)8Ln2Ni(NCO)8 (Ln = Sm, Eu) with three bridging cyanate ligands

Abstract

Syntheses and molecular structures of the first cyanate bridged lanthanide-transition metal complexes, (DMF)8Ln2Ni(NCO)8 and {(DMF)6Ln2Ni(NCO)8} (Ln = Sm, Eu) with three bridging cyanate ligands are reported; magnetic properties of (DMF)8Ln2Ni(NCO)8 (Ln = Sm, Eu) complexes are described.

Article information

Article type
Paper

Chem. Commun., 1998, 2043-2044

The cyanate ion as a bridging ligand between lanthanide and transition metals. Formation of one-dimensional extended arrays {(DMF)6Ln2Ni(NCO)8} (Ln = Sm, Eu) and monomeric complexes (DMF)8Ln2Ni(NCO)8 (Ln = Sm, Eu) with three bridging cyanate ligands

J. Liu, E. A. Meyers, J. A. Cowan and S. G. Shore, Chem. Commun., 1998, 2043 DOI: 10.1039/A804348E

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