The very regioselective twofold cyclopropanation of C60 with a porphyrin bismalonate leads to a C2 symmetrical [60]fullerene–porphyrin dyad with pronounced electronic interactions between the two π–π stacked chromophores.
E. Dietel, A. Hirsch, E. Eichhorn, A. Rieker, S. Hackbarth and B. Röder, Chem. Commun., 1998, 1981 DOI: 10.1039/A804047H
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