SCHEDULED MAINTENANCE
The redox reaction between [VCl2(tmeda)2] (tmeda = N,N,N′,N′-tetramethylenediamine) and benzil yielded the non-oxo VIV benzoin complex [V(tmeda){Ph(O)C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
C(O)Ph}2]·thf (C2 symmetry), the first structurally characterised vanadium–endiolate complex.
M. Farahbakhsh, H. Schmidt and D. Rehder, Chem. Commun., 1998, 2009 DOI: 10.1039/A803393E
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