Issue 13, 1998

Isolation and structural determination of octacyanobutanediide, [C4(CN)8]2–; precursors to M(TCNE)x magnets‡

Abstract

The reaction of MI2·xMe3CN (M = Mn, Fe) and TCNE (tetracyanoethylene) leads to unprecedented [C4(CN)8]2– µ4-metal complexes which have been crystallographically characterized and are precursors to M(TCNE)x·yS magnets.

Article information

Article type
Paper

Chem. Commun., 1998, 1385-1386

Isolation and structural determination of octacyanobutanediide, [C4(CN)8]2–; precursors to M(TCNE)x magnets‡

J. Zhang, R. E. Del Sesto, D. C. Gordon, J. S. Miller, J. Zhang, L. M. Liable-Sands, A. L. Rheingold and B. M. Burkhart, Chem. Commun., 1998, 1385 DOI: 10.1039/A802273I

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