Issue 15, 1998
From the journal:

Chemical Communications

Aerobic enantioselective alkene epoxidation by a chiral trans-dioxo(D4-porphyrinato)ruthenium(VI) complex

Tat-Shing Lai,   Rui Zhang,   Kung-Kai Cheung,   Chi-Ming Che,   Tat-Shing Lai  and  Hoi-Lun Kwong  

Abstract

A dioxoruthenium(VI) complex with a D4-chiral porphyrin ligand has been prepared and characterized by spectroscopic methods and X-ray crystal analysis; the complex exhibits catalytic activity towards aerobic enantioselective epoxidation of prochiral alkenes with enantioselectivity up to 73% ee at an oxygen pressure of 8 atm.

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Article information

DOI
https://doi.org/10.1039/A802009D
Article type
Paper

Chem. Commun., 1998, 1583-1584

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Aerobic enantioselective alkene epoxidation by a chiral trans-dioxo(D4-porphyrinato)ruthenium(VI) complex

T. Lai, R. Zhang, K. Cheung, C. Che, T. Lai and H. Kwong, Chem. Commun., 1998, 1583 DOI: 10.1039/A802009D

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