Issue 9, 1998

Novel mechanistic proposal for the Dötz reaction derived from a density functional study: the chromahexatriene route

Abstract

A new mechanism for the Dötz reaction of vinylcarbene complexes with ethyne proceeds through a chromahexatriene intermediate instead of a vinylketene with smooth energy changes and low energy barriers.

Article information

Article type
Paper

Chem. Commun., 1998, 999-1000

Novel mechanistic proposal for the Dötz reaction derived from a density functional study: the chromahexatriene route

M. Torrent, Chem. Commun., 1998, 999 DOI: 10.1039/A709126E

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