The Rh complex catalysed hydrogenation of an α-(hydroxyalkyl)- N-methoxyacrylamide and the Ru complex catalysed hydrogenation of an α-(fluoroalkyl)acrylate both proceed with ≥90% selectivity to give the syn-isomer.
E. Farrington, M. Comes Franchini and J. M. Brown, Chem. Commun., 1998, 277 DOI: 10.1039/A707025J
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