Peroxo-bridged dinuclear cobalt(III) complexes containing N-glycoside ligands from tris(2-aminoethyl)amine and D-glucose and their reversible dioxygen binding properties
Abstract
Peroxo-bridged dinuclear cobalt(III) complexes containing N-glycoside ligands from tris(2-aminoethyl)amine (tren) and D-glucose (D-Glc), [{Co[(D-Glc)2tren]}2O2]X3·5H2O (X = Cl 2, Br 3), and their reversible dioxygen binding properties are reported [(D-Glc)2tren = bis(N-D-glucosyl-2-aminoethyl)(2-aminoethyl)amine].