Issue 24, 1997

First stereoselective total synthesis of macrocarpal C: structure elucidation of macrocarpal G

Abstract

The first stereoselective total synthesis of macrocarpal C is achieved via a coupling reaction of a silyl dienol ether with a novel hexasubstituted benzene chromium tricarbonyl complex as an optically active benzyl cation equivalent, thereby clarifying the identity of macrocarpal C and G.

Article information

Article type
Paper

Chem. Commun., 1997, 2401-2402

First stereoselective total synthesis of macrocarpal C: structure elucidation of macrocarpal G

T. Tanaka, H. Mikamiyama, K. Maeda, C. Iwata, T. Tanaka, T. Ishida and Y. In, Chem. Commun., 1997, 2401 DOI: 10.1039/A705231F

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