Issue 24, 1997

Synthesis of the naturally occurring [3.3.3]propellane (±)-modhephene featuring a photocycloaddition–reductive fragmentation diquinane construction

Abstract

Modhephene has been synthesized in 11 steps and 21% overall yield from cyclopentadiene, by a stereoselective route that features a photocycloaddition–fragmentation sequence for the construction of the diquinane core.

Article information

Article type
Paper

Chem. Commun., 1997, 2381-2382

Synthesis of the naturally occurring [3.3.3]propellane (±)-modhephene featuring a photocycloaddition–reductive fragmentation diquinane construction

C. A. Dvorak and V. H. Rawal, Chem. Commun., 1997, 2381 DOI: 10.1039/A704260D

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