The reaction of [Ru(CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.
A. F. Hill, C. T. Ho and J. D. E. T. Wilton-Ely, Chem. Commun., 1997, 2207 DOI: 10.1039/A704157H
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