Synthesis of µ-oxo-bridged group 15 element–aluminium heterodinuclear porphyrins [(oep)(Me)M–O–Al(oep)]ClO4 (M=P, As, Sb) and X-ray crystal structure of [(oep)(Me)As–O–Al(oep)]ClO4

Abstract

µ-Oxo-bridged group 15 element–aluminium heterodinuclear porphyrins, [(oep)(Me)M–O–Al(oep)]ClO ₄ (M=P, As, Sb), are synthesized by the reaction of [(oep)(Me)M(OH)]- ClO ₄ with (oep)AlMe.