Issue 14, 1997

A tetranuclear cluster sandwiched between edge-bridging cycloheptatrienyl rings: the synthesis and characterisation of [Ru4(CO)7(µ-C7H7)2 ]

Abstract

The reaction of [Ru 3 (CO) 12 ] with cycloheptatriene affords [Ru 4 (CO) 7 (µ-C 7 H 7 ) 2 ] an example of a new class of sandwich cluster which is characterised in the solid-state by single-crystal X-ray diffraction and shown to contain an unusual arrangement of two parallel edge-bridging organic rings.

Article information

Article type
Paper

Chem. Commun., 1997, 1259-1260

A tetranuclear cluster sandwiched between edge-bridging cycloheptatrienyl rings: the synthesis and characterisation of [Ru4(CO)7(µ-C7H7)2 ]

D. Braga, P. J. Dyson, F. Grepioni, B. F. G. Johnson, C. M. Martin, L. Scaccianoce and A. Steiner, Chem. Commun., 1997, 1259 DOI: 10.1039/A702448G

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