Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionlised trifluoromethyl ketones in good yields.
M. Denieul, B. Quiclet-Sire and S. Z. Zard, Chem. Commun., 1996, 2511 DOI: 10.1039/CC9960002511
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