Issue 21, 1996

An efficient synthetic route to primary and secondary condensation products of silanetriols starting from (arylamino)trichlorosilanes

Abstract

Stoichiometry dependent hydrolysis of (arylamino)-silyltrichlorides using anhydrous N2H4 as the HCl acceptor and dehydrating agent leads to the formation of the primary and secondary condensation products of silanetriols, tetrahydroxydisiloxanes [Ar(SiMe3)NSi(OH)2]2O and cyclotrihydroxytrisiloxanes [Ar(SiMe3)NSi(OH)O]3, respectively.

Article information

Article type
Paper

Chem. Commun., 1996, 2417-2418

An efficient synthetic route to primary and secondary condensation products of silanetriols starting from (arylamino)trichlorosilanes

R. Murugavel, P. Böttcher, A. Voigt, M. G. Walawalkar, H. W. Roesky, E. Parisini, M. Teichert and M. Noltemeyer, Chem. Commun., 1996, 2417 DOI: 10.1039/CC9960002417

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