The coadsorption of methanol rich, dioxygen–methanol mixtures at Cu(110) surfaces is shown to result in an adlayer consisting entirely of a single state of chemisorbed methoxy species; this confirms that a second more strongly adsorbed state of methoxy, observed in the presence of preadsorbed oxygen, is stabilised by the chemisorbed oxygen.
P. R. Davies and G. G. Mariotti, Chem. Commun., 1996, 2319 DOI: 10.1039/CC9960002319
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