Issue 19, 1996
From the journal:

Chemical Communications

Redox-induced κ2–κ3 isomerisation in rhodium hydrotris(3,5-dimethylpyrazolyl)borate chemistry: the stabilisation of square-pyramidal rhodium(II)

Neil G. Connelly,   David J. H. Emslie,   Bernhard Metz,   A. Guy Orpen  and  Michael J. Quayle  

Abstract

One-electron oxidation of the square-planar, 16-electron complex [Rh(CO)(PPh3)(κ2-Tp′)] with [FeCp2][PF6] gives the square-pyramidal RhII complex [Rh(CO)(PPh3)(κ3-Tp′)][PF6] in which the third pyrazolyl group of Tp′ is N-bound in the axial position by a three-electron two-centre bond (Rh–Naxial 0.13 Å longer than Rh–Nbasal).

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Article information

DOI
https://doi.org/10.1039/CC9960002289
Article type
Paper

Chem. Commun., 1996, 2289-2290

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Redox-induced κ2–κ3 isomerisation in rhodium hydrotris(3,5-dimethylpyrazolyl)borate chemistry: the stabilisation of square-pyramidal rhodium(II)

N. G. Connelly, D. J. H. Emslie, B. Metz, A. G. Orpen and M. J. Quayle, Chem. Commun., 1996, 2289 DOI: 10.1039/CC9960002289

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