The hexafunctional initiator 5 has been synthesized and used for the living cationic polymerization of isobutene by means of the core-first method, giving rise to the first hexa-arm polyisobutene stars 6.
E. Cloutet, J. Fillaut, Y. Gnanou and D. Astruc, Chem. Commun., 1996, 2047 DOI: 10.1039/CC9960002047
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