Various applications of a chiral cyclopentadiene in chiral recognition experiments are reported. Racemic cyclic dienophiles undergo very efficient kinetic resolution while with prochiral cyclohexadienones discrimination of enantiotopic groups is observed. In one particular case a racemic exo-methylene lactone from to a highly stereospecific cycloaddition yielded to topographic resolution.
C. Borm, D. Meibom and E. Winterfeldt, Chem. Commun., 1996, 887 DOI: 10.1039/CC9960000887
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