Issue 5, 1996

Preparation of some new anomeric carbohydrate difluoromethylenephosphonates via phosphonyl radical addition to gem-difluoroenol ethers

Abstract

Generation of a phosphonyl radical either from diethyl phosphite, or diethyl (phenylselenyl)phosphonate in conjunction with tributylstannane, in the presence of a carbohydrate gem-difluoroenol ether provides a new route to anomeric difluoromethylenephosphonates; in the course of these reactions, some unusual stereochemical effects are observed.

Article information

Article type
Paper

Chem. Commun., 1996, 613-614

Preparation of some new anomeric carbohydrate difluoromethylenephosphonates via phosphonyl radical addition to gem-difluoroenol ethers

T. F. Herpin, J. S. Houlton, W. B. Motherwell, B. P. Roberts and J. Weibel, Chem. Commun., 1996, 613 DOI: 10.1039/CC9960000613

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