Issue 24, 1995

Characterization of persistent α,ω-diphenyl substituted allyl cations within monodirectional acid zeolites

Abstract

Two α,ω-diphenyl substituted allylic cations are generated within ZSM-5 and mordenite as persistent species by adsorption of 1-acetoxy-1,3-diphenylpropane and 1,5-diacetoxy-1,5-diphenylpentane onto the H+-form of these zeolites; the diffuse reflectance spectra of these highly coloured samples (orange or pink) matches the very characteristic absorption spectra of these allyl cations in homogeneous solution; the non-acidic Na+-form of these zeolites does not have the same effect.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2477-2478

Characterization of persistent α,ω-diphenyl substituted allyl cations within monodirectional acid zeolites

M. L. Cano, V. Fornés, H. García, M. A. Miranda and J. Pérez-Prieto, J. Chem. Soc., Chem. Commun., 1995, 2477 DOI: 10.1039/C39950002477

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements