Issue 21, 1995

A novel highly diastereoselective synthesis of chiral dihydrothiophenes from mesoionic compounds

Abstract

Thioisomünchnones undergo 1,3-dipolar cycloaddition with chiral nitroalkenes to afford stereoselectively 4,5-dihydrothiophenes by means of an unprecedented fragmentation of cycloadducts; the structures of these products have been established by single crystal X-ray structure analyses.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2213-2214

A novel highly diastereoselective synthesis of chiral dihydrothiophenes from mesoionic compounds

M. Avalos, R. Babiano, A. Cabanillas, P. Cintas, M. J. Diánez, M. D. Estrada, J. L. Jiménez, A. López-Castro, J. C. Palacios and S. P. Garrido, J. Chem. Soc., Chem. Commun., 1995, 2213 DOI: 10.1039/C39950002213

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