Issue 13, 1995

Enzymatic activity catalysing exo-selective Diels–Alder reaction in solanapyrone biosynthesis

Abstract

The crude enzyme from Alternaria solani is able to catalyse the [4 + 2] cycloaddition of prosolanapyrone III 6 to the exo adduct solanapyrone A 1 whose optical purity is estimated as 92 ± 8% e.e. by HPLC analysis monitored using a CD spectrometer; this enzyme also catalyses the oxidation and [4 + 2] cycloaddition of prosolanapyrone II 5 to 1 with 99 ± 4% e.e.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1321-1322

Enzymatic activity catalysing exo-selective Diels–Alder reaction in solanapyrone biosynthesis

H. Oikawa, K. Katayama, Y. Suzuki and A. Ichihara, J. Chem. Soc., Chem. Commun., 1995, 1321 DOI: 10.1039/C39950001321

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