Issue 11, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Oxidative cleavage of the Te–Te bond in η2-ditellurido complexes: syntheses and structures of M(PMe3)4(η2-Te2)H2(M = Mo, W)

Vincent J. Murphy,   Daniel Rabinovich,   Shannon Halkyard  and  Gerard Parkin  

Abstract

The η2-ditellurido derivatives, M(PMe3)4(η2-Te2)H2(M = Mo, W) are synthesized by the reactions of M(PMe3)5H2 with elemental tellurium; the conversion of M(PMe3)4(η2-Te2)H2 to the terminal tellurido complexes M(PMe3MTe)2provides an unprecedented example of a transformation that involves oxidative cleavage of a ditellurido ligand at a single metal centre.

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Article information

DOI
https://doi.org/10.1039/C39950001099
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1099-1100

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Oxidative cleavage of the Te–Te bond in η2-ditellurido complexes: syntheses and structures of M(PMe3)4(η2-Te2)H2(M = Mo, W)

V. J. Murphy, D. Rabinovich, S. Halkyard and G. Parkin, J. Chem. Soc., Chem. Commun., 1995, 1099 DOI: 10.1039/C39950001099

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