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Issue 6, 1995
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Predominance of unrearranged products in the reactions of the iodide (Me3Si)3CSi(CD3)2I with silver salts, and its mechanistic implications

Abstract

In the title reactions, unrearranged products (Me3Si)3C[Si(CD3)2Y] usually predominate over their rearranged isomers (Me3Si)2C[Si(CD3)2Me](SiMe2Y), revealing the inadequacy of the simplest mechanistic picture in which the two bridged silicon centres in a methyl-bridged cationic intermediate are equally available for attachment of a nucleophile.

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Article type: Paper
DOI: 10.1039/C39950000705
Citation: J. Chem. Soc., Chem. Commun., 1995,0, 705-706
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    Predominance of unrearranged products in the reactions of the iodide (Me3Si)3CSi(CD3)2I with silver salts, and its mechanistic implications

    A. I. Almansour, J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer, J. Chem. Soc., Chem. Commun., 1995, 0, 705
    DOI: 10.1039/C39950000705

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