A low-lying S= 15/2 ground state in a heptanuclear CrIIINiII6 species arises from the ferromagnetic interaction (J= 16.8 cm–1) between one central CrIII(S= 3/2) and six peripheral NiII(S= 1) ions through the cyanide bridge.
T. Mallah, C. Auberger, M. Verdaguer and P. Veillet, J. Chem. Soc., Chem. Commun., 1995, 61 DOI: 10.1039/C39950000061
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